OPTIMIZATION OF SODIUM VANADATE (NVO) AS CATHODE MATERIAL FOR ZINC-ION BATTERIES
Larry, Max
Promoteur(s) : Boschini, Frédéric
Date de soutenance : 20-jan-2021 • URL permanente : http://hdl.handle.net/2268.2/11745
Détails
Titre : | OPTIMIZATION OF SODIUM VANADATE (NVO) AS CATHODE MATERIAL FOR ZINC-ION BATTERIES |
Auteur : | Larry, Max |
Date de soutenance : | 20-jan-2021 |
Promoteur(s) : | Boschini, Frédéric |
Membre(s) du jury : | Mahmoud, Abdelfattah
Cloots, Rudi Hatert, Frédéric |
Langue : | Anglais |
Mots-clés : | [en] Zinc-ion battery [en] Sodium vanadate [en] ZIB [en] NVO [en] Na0.33V2O5 [en] Na1.1V3O7.9 [en] triflate [en] aqueous electrolyte [en] liquid pathway [en] stirring [en] hydrothermal [en] calcination [en] thermal treatment [en] XRD [en] SEM [en] specific capacity [en] cycle number [en] stability [en] pillars [en] sodium ions |
Discipline(s) : | Physique, chimie, mathématiques & sciences de la terre > Chimie |
Public cible : | Chercheurs Professionnels du domaine Etudiants |
Institution(s) : | Université de Liège, Liège, Belgique |
Diplôme : | Master en sciences chimiques, à finalité spécialisée |
Faculté : | Mémoires de la Faculté des Sciences |
Résumé
[en] In this paper, the optimization of sodium vanadate (NVO) as cathode material for zinc-ion batteries (ZIBs) and the improvement of the material's synthesis are reported. Following the convincing capacities obtained for ZIBs using vanadium pentoxide (V₂O₅) as a cathode material, it is tried to further enhance the latter’s electrochemical performances through the insertion of sodium ions into the crystallographic structure of V₂O₅. Acting as stabilizing pillars, the added sodium ions allow NVO cathode material to reach extremely high cycling numbers without a considerable loss of capacity. Special attention is paid to the ecological aspect of the synthesizing method, as ZIBs are considered as being a sustainable and eco-friendly alternative to LIBs.
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